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課程名稱 |
物理化學一
PHYSICAL CHEMISTRY (I) |
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開課學期 |
98-1 |
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授課對象 |
化學工程學系 |
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授課教師 |
戴子安 |
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課號 |
ChemE2005 |
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課程識別碼 |
504 26110 |
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班次 |
01 |
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學分 |
3 |
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全/半年 |
半年 |
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必/選修 |
必修 |
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上課時間 |
星期一3,4(10:20~12:10)星期四2(9:10~10:00) |
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上課地點 |
普303普303 |
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備註 |
限本系所學生(含輔系、雙修生)
總人數上限：62人 |
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Ceiba 課程網頁 |
http://ceiba.ntu.edu.tw/981pchem |
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課程簡介影片 |
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核心能力關聯 |
核心能力與課程規劃關聯圖 |
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課程大綱
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為確保您我的權利,請尊重智慧財產權及不得非法影印
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課程概述 |
物理化學（一）、（二）
學分數：3、3
一、 課程大綱：
1. Zeroth Law of Thermodynamics
2. First Law of Thermodynamics
3. Second and Third Laws of Thermodynamics
4. Fundamental Equations of Thermodynamics
5. Chemical Equilibrium
6. Phase Equilibrium
7. Electrochemical Equilibrium
9-10. Quantum Theory and Atomic Structure
13-14. Rotational, Vibrational and Electronic Spectroscopy
17. Kinetic Theory of Gases
18. Experimental Kinetics and Gas Reactions
19. Chemical Dynamics and Photochemistry
20. Kinetics in the Liquid Phase
二、 教科書：Physical Chemistry, by Silbey/Alberty/Bawendi 4th Ed, Wiley
三、 預修課程：普通物理，普通化學
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課程目標 |
This course is an introduction to chemical thermodynamics, quantum mechanics and chemical kinetics with application to gases, solutions, phase equilibria to provide a firm foundation for understanding the physical principles that govern chemical and biological systems. |
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課程要求 |
Grades: 2 exams each 25%
final 30%
homework + quiz 20%
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預期每週課後學習時數 |
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Office Hours |
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指定閱讀 |
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參考書目 |
Text book: Physical Chemistry 4th Edition Wiley by Silbey/Alberty/Bawendi
Reference book: 1. Physical Chemistry, 8th Edition Oxford by Atkins/de Paula
2. Physical Chemistry, Pearson Publishing by Engel/Reid |
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評量方式
(僅供參考) |
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No. |
項目 |
百分比 |
說明 |
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1. |
作業 and 隨堂小考 |
20% |
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2. |
期末考 |
30% |
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3. |
期中考(1th,2nd) |
50% |
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週次 |
日期 |
單元主題 |
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第1週 |
9/14,9/17 |
9/14:Chapter 1 Zero Law of Thermodynamics and Equation of State 1.1 State of a System, 1.2 Zeroth Law of Thermodynamics, 1.3 and 1.4 Ideal Gas Mixture and Dalton's Law
9/17:1.5 Real Gases and The Virial Equation 1.6 P-V-T Surface for a One-Componet System |
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第2週 |
9/22,9/25 |
9/22: 1.7 critical phenomena 1.8 the van der Waals 1.9 The Principle of Corresponding States 9/25: 1.10 Partial Molar Properties, 1.11 Barometric Formula |
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第3週 |
9/28,10/01 |
9/28: Chapter 2 First Law of Thermodynamics 2.1 and 2.2 Work and Heat 2.3 Exact and Inexact Differentials 10/1: 2.4 Work of Compression and Expansion of a Gas at Constant Temperature |
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第4週 |
10/05,10/08 |
10/5: 2.5 Various Kinds of Work 2.6 Change in State at Constant Volume 2.7 Enthalpy and Change of State at Constant Pressure 10/08: 2.8 Heat Capacities |
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第5週 |
10/12, 10/15 |
10/12: 2.9 Joule-Thomson Expansion, 2.10 Adiabatic Process with Gases, 2.11 Thermochemistry 10/15: 2.12 Enthalpy of Formation |
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第6週 |
10/19,10/22 |
10/19: 2.13 Calorimetry. 10/22: Chapter 3 - The Second and Third Laws of Thermodynamics 3.1 Entropy as a State Function |
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第7週 |
10/26,10/29 |
10/26: 1st Exam; 10/29: 3.2 the second law of Thermodynamics |
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第8週 |
11/02,11/05 |
11/2: 3.3 Entropy Changes in Reversible Process 3.4 Entropy Change in Irreversible Process 11/5: 3.5 Entropy of Mixing Ideal Gases 3.6 Enropy and Statistical Probability |
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第9週 |
11/9,11/12 |
11/9: 3.7 Calorimetric Determination of Entropies 3.8 The 3rd Law of Thermodynamics 3.9 Special Topics-Carnot Heat Engine 11/12: Chapter 4 Fundamental Equations of Thermodynamics 4.1 The Combined First and Second Laws |
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第10週 |
11/16,11/19 |
11/16: 4.2 Definition of Additional Thermodynamic Potentials Using Legendre Transforms 11/19: 4.3 Effect of Temperature on the Gibbs Energy 4.4 Effect of Pressure on the Gibbs Energy |
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第11週 |
11/23,11/26 |
11/23: 4.5 Fugacity and Activity 4.6 The Significance of the Chemical Potential 11/26: Additive of Partial Molar Properties with Applications to Ideal Gases |
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第12週 |
11/30,12/03 |
11/30: 4.8 Gibbs-Duhem Equation 4.9 Special Topic: Maxwell relation, Chapter 5 Chemical Equilibrium 5.1 Derivation of the General Expression 12/03: 5.2 Equilibrium Constant Expression for Gas Reactions |
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第13週 |
12/07,12/10 |
12/07: 2nd Exam 12/10: 5. 3 Determination of Equilibrium Constant |
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第14週 |
12/14,12/17 |
12/14: 5.4 Use of Standard Gibbs Energies of Formation to Calculate Equilibrium Constants 5.5 Effect of Temperature on Equilibrium Constants 5.6 Effect of Pressure, Initial Composition, and Insert Gases on the Equilibrium Composition 5.7 Equilibrium Constants for Gas Reactions Written in Terms of Concentrations 12/17: 5.8 Heterogeneous Reactions 5.9 Phase Components, Degree of Freedome and the Phase Rule |
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第15週 |
12/21,12/24 |
12/21: Chapter 6 Phase Equilibrium 6.1 Phase Diagrams of One-Component Systems 12/24: 6.2 The Clapeyron Equation 6.3 The Clausius-Clapeyron Equation |
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第16週 |
12/28,12/31 |
12/28: 6.4 Vapor-Liquid Equilibriumof Binary Liquid Mixture 6.5 Vapor Pressure of Nonideal Mixture and Henry's Law 12/31: 6.6 Activity Coefficients |
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第17週 |
1/04,1/07 |
1/4: 6.7 Colligative Properties 6.8 Two Component Systems Consisting of L/L, V/L and L/S Phases 1/7: 6.9 Effect of Surface Tension on the Vapor Pressure |
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